![]() ![]() All of the research shows tomatoes are indeed pure heart and blood food. Start by thinking about these and then move into saying no.Ī sliced Carrot looks like the human eye The pupil, iris and radiating lines look just like the human eye.and YES science now shows that carrots greatly enhance blood flow to and function of the eyes.Ī Tomato has four chambers and is red. Make a list of five things you'd like to say no to. At the end of the week, tally up the number…surprised? Awareness is the first step to realigning your decisions and priorities. Start now.įor one week, keep track of how many times you say yes to something that is not on your Absolute Yes List. You might say something like: "I'm sorry, but it's just not possible for me to do that," or, "I'll have to decline but thank you anyway." As you practice saying no, it will get easier. Don't over-explain or defend your decision. Your self-care is always a valid excuse to say no. If saying no is difficult (especially to family members), then make sure you speak to your partner for support before and after you decline a request. Although it may feel uncomfortable to think about saying no, it's important to remember that each time you say yes to someone or something else, you say no to you and your priorities. Once you have created your "Absolute Yes List," the top priorities in your life, it becomes easier to identify those things that you'll need to let go. Get used to hearing yourself say the word, and then you'll be ready to use it with other people!įinding yourself is not about what you add to your life, it's about what you take away. ![]() But practice makes perfect, so start now! You can try it in the mirror, or even walk around the house saying it. I'll call you back and let you know." This will give you time to evaluate the situation and decide if it's something you truly want to do.įor many women, saying "No" doesn't come naturally. Say, "Let me think about it" or "I have to take care of something right now. The next time you're asked to do something, don't answer right away. Don't feel that you're being selfish you have a responsibility to yourself to take care of your needs. Use this opportunity to tune in to what you want and need. Schedule time away from your job, your partner and your children. Irregular red lines at the base of the nail fold - Possible Lupus/connective tissue problemsĭark lines beneath the nail - Possible interior skin problems "Clubbing," a painless increase in tissue around the ends of the fingers, or inversion of the nail - Possible Lung problems Pitting or rippling of the nail surface - Possible Psoriasis or inflammatory problems Pale or white nail beds - Possible Anemia/Blood problems Half-white, half-pink nails - Possible Kidney problems ![]() Yellowish nails with a slight blush at the base - Possible Diabetes White nails - Possible Liver problems or`Lung problems Taking a good look on our health condition~ our body tells us how it is functioning~ eyes, nails, tongue.Ĭlues About Fingernail color and texture can reflect a wide range of medical conditions The name “Esther” comes from the Persian word: "star". King Xerxes chose Esther to be his wife and queen. She was given anything she wanted to take with her from the harem to the King's palace. Esther was advanced for this role by Mordecai, her cousin and guardian.įor 12 months each woman underwent beauty treatments in the harem, after which she would go to the King. Beautiful young women were gathered to the palace from every province. The King followed this advice, then began searching for a new queen by means of a beauty contest. Furious at her refusal to obey, the King asked his wise men and the seven princes of Persia for advice, according to the law they advised the King to search for a new queen. But when the attendants delivered the king's command, Queen Vashti refused to come. The King ordered his queen Vashti to appear before him and his guests wearing her crown, to show off her beauty. According to the Biblical Book of Esther King Xerxes of Persia held a one hundred and eighty-day feast in Susa to display the vast wealth of his kingdom and the splendor and glory of his majesty. As a result of Esther's intervention and influence, Jews lived in the Persian Empire for 2400 years thereafter.Įsther's husband Xerxes (Ahasuerus) followed in the footsteps of Cyrus the Great, in showing mercy to the Jews of Persia. She was Persia's first Jewish queen and heroine of the Biblical Book of Esther which is named after her. Esther, born Hadassah, was the wife of Xerxes the Great and the Shahbanu of the Persian Empire. ![]()
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![]() ![]() Asking questions about the person you're talking to makes you instantly more likable than the person who just wants to talk about themselves. Get to know what they do and what they like. Have your 30-second elevator pitch ready, but after that, shift the focus off of you. They'll likely ask you about yourself, but be sure to also ask about them as well. As opportunities arise throughout the day to talk to people, do so. ![]() Be friendlyīeing friendly is one of the best, and easiest, ways to make a good impression at a new job. ![]() If you've been provided answers to questions, be sure to listen so you don't have to ask the same questions over and over again, as well. Chances are that others have similar questions as you, so don't be afraid to ask.Īt the same time, show initiative by doing your own research before you begin commenting or making suggestions that might be interpreted as not understanding your position or the organization. No one expects you to be a pro when you are new to a job, and no one expects you to know everything about the organization right away either. It's better to get the information you need to handle things correctly than to learn the hard way that you're doing something wrong. Don't be afraid to ask questions to gain clarity when you need it. From how to do your job effectively to how the organization works, it's natural to feel overwhelmed with all this new information you are expected to retain. Chances are the answers are in those orientation materials. Before your first day of work, think about what kinds of things you want to know about your new job and company. On the flip side, it could also happen that your new company hands you a bunch of orientation materials and then leaves you alone. The type of boss that likes to start things off that quickly usually wants to see how well you can handle yourself on the fly. Ask questions, but don't be afraid to do some problem solving on your own. If that ends up being the case, be ready to jump in and show your stuff. Our best new-job advice: Be ready for anything! Some supervisors like to start out new hires by throwing them into the fire. If you need a little help, there are lots of great phone apps to make your commute a little easier. Showing up a little early is OK, but being late on day one starts things off on the wrong foot in a big way. However long your commute will take you, leave at least 10 minutes early on your first real day of work. If you really want to be safe, get up one morning and give it a test run. Pay attention to how much traffic is on your route during the morning commute. One of the smartest things to do before starting a new job is to map out the best route to your new workplace in advance. This one simple step can save you a lot of embarrassment and help you make a good first impression. You'd rather be a little too dressy than too casual. If you have any doubts, always err on the side of formal when choosing your ensemble for your first day of work. Whatever you see, you want to dress accordingly to ensure that your outfit is appropriate for your new job. Is your new company business casual or business formal? Maybe this company is more laid back and jeans are the norm. ![]() When planning your first day of work outfit, your first stop should be the company website and social media pages. It's a lot, we know, but don't stress! Just get yourself ready to rock the first day of your new job with these simple tips. Your very first day of work is crucial - your first impression can set the tone for how your boss and your co-workers see you. That means it's time to get focused and make the most of this opportunity right out of the gate. You got the call, negotiated a salary, and finally landed the job you've been trying to nail down - congratulations! This is the time for optimism and excitement after all, this could be the job that truly launches your career. Play your cards right on your first day at a new job and you'll be sure to make a great impression. ![]() ![]() ![]() The gods are dead, the sun no longer falls or rises, there will be no more Varl, even the serpent that is supposed to devour the world is confused as to what is happening. We saw how races and people all struggled with and reacted to the coming end. Jorundr seems to reference a Swedish king of the same name. Most stories involve passing the torch to the next generation however in the Banner Saga there is a very strong thematic sense of the end. Banner Saga was about the tenacious struggle to survive in a world that was ending, we followed a few no-bodies from a small no-where hamlet from one side of the known world to another.Even as Hakon and Ubin witness the burning remains. In the first part of The Banner Saga, end of Chapter 3, Grofheim is overrun and destroyed by a sudden and overwhelming dredge invasion coming from the north. He is the fifth king of the varl, ruling from the capital of Grofheim. The survivors confirm that Jorundr was indeed slain in the fall of the fortress-city. Jorundr is a varl non-playable character (NPC) met in the first part of The Banner Saga. Later in the game, in the second part of The Banner Saga ( Chapter 13), the Ravens meet Fasolt and a small company of varl, flying the colors of Einartoft. ![]() With the unknown fate of the fifth varl king and with Vognir mysteriously killed, the varl kingship passes on to Hakon. Einartoft eventually falls to the dredge, led by Bellower himself. His resolve is broken only by the intervention of a legendary varl hero.Īs the Skogr caravan departs together with Eyvind ( Chapter 6), Jorundr decides to have the varl make a last stand in Einartoft, but not before sending off a warband lead by Hakon to Arberrang, the human capital in the south, to seek the aid of King Meinolf. The varl king stubbornly refuses, relying on Fasolt to hold the bridge whatever the cost. Ending 82 The Banner Saga Developer: Stoic Studios Publisher: Versus Evil Steam 2014 This game is beautiful, poignant, thoughtful and oozes aesthetic class. Juno leads you to go get something for the end of the game. Eyvind and Rook implore Jorundr to allow them to bring down the monumental varl bridge of Einartoft in order to prevent or, at least, delay the sacking of the city. Rook's caravan reaches Einartoft ( Chapter 4), shortly after Hakon's caravan and just as the dredge army descends and lays siege to the fortress-city. Even as Hakon and Ubin witness the burning remains of the varl capital from the Two Spears, Jorundr is wounded but manages to escape, leading the remnants of the varl to Einartoft, the ancient fortress-city to the south. Jorundr is a varl non-playable character (NPC) met in the first part of The Banner Saga. Jorundr as seen in Einartoft, wounded but escaped from the sacking of Grofheim. ![]() ![]()
![]() ![]() ![]() Cons Seasons can get really dry for work. Pros You create your schedule and set your price. Thus meaning the only conns is the benefits and if there is a dry season, its going to hurt big time. The work you do and when you do it is in your hands. That said, if you charge around $23 per hour to complete a task, you should be able to recoup your registration fee in almost no time.Ĭatch up on Select's in-depth coverage of personal finance, tech and tools, wellness and more, and follow us on Facebook, Instagram and Twitter to stay up to date. Task rabbit is a job for people wanting to create their own schedule and adjust their own prices. One downside, though, is the $25 registration fee that every Tasker is required to pay before they can get their profile approved and start accepting jobs. And, of course, you can also collect testimonials from those clients. For those who are just starting out or hope to use their skills to start a business, TaskRabbit offers the opportunity to scale your services quickly since clients you find through the app could become repeat clients who reach out to you in the future - on or off the app - to retain your services again. If you're looking for an easy way to build a local clientele by using skills you already possess, TaskRabbit might help you earn a decent amount of extra money, especially if the tasks involve work around the client's home. Investing +More All Investing Best IRA Accounts Best Roth IRA Accounts Best Investing Apps Best Free Stock Trading Platforms Best Robo-Advisors Index Funds Mutual Funds ETFs Bonds Help for Low Credit Scores +More All Help for Low Credit Scores Best Credit Cards for Bad Credit Best Personal Loans for Bad Credit Best Debt Consolidation Loans for Bad Credit Personal Loans if You Don't Have Credit Best Credit Cards for Building Credit Personal Loans for 580 Credit Score Lower Personal Loans for 670 Credit Score or Lower Best Mortgages for Bad Credit Best Hardship Loans How to Boost Your Credit Score Taxes +More All Taxes Best Tax Software Best Tax Software for Small Businesses Tax Refunds a Tasker would need to work forty hours a week at 45/hour or twenty. TaskRabbit is a website and mobile app that allows users to outsource small jobs and tasks to. or 36,000 a year.57 TaskRabbit has promoted the idea that Taskers who work. Small Business +More All Small Business Best Small Business Savings Accounts Best Small Business Checking Accounts Best Credit Cards for Small Business Best Small Business Loans Best Tax Software for Small Business Empowering Taskers to deliver an improved customer experience. What reviewers want you to know Positive highlights Critical highlights Excellent tasker, John H, responded quickly to my job offer Business is a scam. Personal Finance +More All Personal Finance Best Budgeting Apps Best Expense Tracker Apps Best Money Transfer Apps Best Resale Apps and Sites Buy Now Pay Later (BNPL) Apps Best Debt Relief Best Mortgages for Average Credit Score.Best Loans to Refinance Credit Card Debt. ![]() ![]() The only proton expected to correlate with three nonequivalent protons is proton 9! Chemical Shift Look at the table for any clear differences in correlation and begin there! In this example, all unassigned protons show one or two COSY correlations-except the proton at 4.233 ppm, which correlates to three other protons by COSY. My favorite way to analyze a COSY spectrum with many unassigned protons is to make a table of correlations, like the one seen here. The remaining protons are doublets, triplets, and multiplets that can be assigned by 2-dimensional COSY. The peak also integrates to 1 proton, supporting the assignment. The chemical shift of 11.256 ppm supports this assignment, as imide protons often show up far downfield. ![]() The only proton that should show up as a singlet is proton 6, as it has no neighboring protons that would split the peak (the nearest proton is 5 bonds away!). There is only one singlet in the ¹H-NMR spectrum. Therefore, the peak at 7.690 ppm must represent proton 4! The integration and chemical shift support the assignment, as proton 4 is the only aromatic proton in the structure. The long-range coupling constant observed for proton 3 (J=1.2 Hz, split into a doublet by proton 4) is reflected in the coupling constant for proton 4 (J=1.2 Hz, split into a quartet by proton 3). Protons that are coupled to each other should exhibit the same coupling constant. The peak is split into a doublet with a coupling constant of 1.2 Hz, reflecting the long-range coupling between protons 3 and 4, which also supports this assignment. The high field chemical shift supports this assignment. The only peak with an integration of 3 is the doublet at 1.770 ppm. ![]() Proton 3 is the only methyl group in the structure, and therefore must integrate to 3 protons. ![]() ![]() You can combine RealTimes with filters and effects from other platforms, and create social media art. It sorts pictures automatically, which means it is time-saving as well. This app creates breathtaking, slideshow stories. Realplayer is the best alternative for social media enthusiasts. Its handheld counterpart, RealTimes, is available for all kinds of phones: Android and iOS. Where can you run this program?Ĭurrently, RealPlayer is only compatible with Windows. Even if your followers don’t use this software, they’ll see the slideshow which this app made possible. RealPlayer is not bound to a specific device or platform. If you believe that a particular filter from another platform suits a picture or video better, you can use it freely. The benefits of social media connection don’t stop there. Publish a slideshow, and all of your followers receive a notification about it. You can also synchronize with your social media. One downside is that RealPlayer favors faces, this means that the program can overlook some good shots. This app works on an algorithm that scans pictures and videos the moment you take them. Tweak the final compilation, so it suits your taste perfectly. RealPlayer cannot publish slideshows without your approval. RealPlayer automatically creates slideshows, but that does not mean that one program has complete control over your future posts. However, there are those pictures and videos that spend their whole lives trapped inside phones and PCs. Our best, sometimes the worst, pictures and videos see the world beyond phones and computers. ![]() ![]() RealPlayer is a multimedia player focusing on visual storytelling. Only the best pieces contribute to the final compilation. It is worth noting that the UI is not friendly enough for both video playback and file management.The perfect way to create slideshows from videosĭuplicates, blurry, and dark shots are left out from the slideshows. RealPlayer RealTimes 2022 includes all the necessary files to run perfectly on your system, uploaded program contains all latest and updated files, it is full offline or standalone version of RealPlayer RealTimes 2022 Free Download for compatible versions of Windows, download link at the end of the post. And as same as complained by the CNET users, we also get endless signup alters to RealTimes. It just failed the download task and generally unable to respond to drag-n-drop videos (even WMP can respond quickly). We also encountered several download problems using its download plug-in on firefox Windows 7 system. Common RealPlayer Windows 7/10 ProblemsĪfter hands-on test of RealPlayer on Windows 7, we advice users do mind those buttons at installation setups, like "Agree" button which might trick you into installing Norton software. So if you are looking for a strong media player that is lightweight and capable of dealing with other formats like divx HEVC 4K 8K high-res videos, you may have to look away. RealPlayer at present only supports playback of m4a, mp3, wma, ra, rv, rm, ram, mvb, wav, flv, 3gp, 3gp2, mp4, m4v, wmv, iv4, avi, MPEG-4, QCELP, EVRC. Its emphasis on strong playback ability has been diluted by all the other seemingly attractive utilities yet requiring you to sign in. RealPlayer has transformed itself into more than just a media player – a video photo editor, a file transferor, a web video downloader, a DVD burner, a share software etc. * Interface is totally confusing." - commented by an Anonymous on CNET * Downloader rarely works, and with only one or two browsers at that. *Constantly asks you to set up an account, when you start it, and everytime a looping video replays (years ago I paid for advanced level Real Player features, but they apparently cancelled that contract unilaterally) " * No private - wants all your stuff in the cloud, ![]() RealPlayer Free Download Windows 7/10 Review ![]() ![]() Step 2: The initial temperature of this solvent is recorded, T i.Step 1: An accurately known quantity of water (the solvent) is placed in a well insulated vessel (eg, a polystyrene foam or styrofoam™ cup).(ii) the only energy being absorbed by the reaction is that from the water in the cup and not from the surrounding environment in the case of an endothermic reaction. (i) all the energy released by the reaction is used to raise the temperature of the water in the cup and is not lost in heating the surrounding environment in the case of an exothermic reaction In this experiment the polystyrene foam (styrofoam™) cup is used as an insulated vessel in which to conduct the experiment so that either: Polystyrene foam (styrofoam™) is a good insulator, that is, it is a material that does not conduct heat well. The following describes the use of a polystyrene foam (styrofoam™) cup as a calorimeter to determine the heat of solution of a salt (solid solute) in water (the solvent). ΔH hyd |ΔH hyd| then ΔH soln is positiveĮxperiment to Determine the Molar Heat of Solution (Molar Enthalpy of Solution) of a Solute Hydration is usually exothermic, so heat is released when water molecules completely surround solute particles. When water is used as the solvent, we use the term hydration energy, ΔH hyd, rather than the more general term solvation energy. Solvation energy, ΔH solv is the energy released or absorbed when solute particles are completely surrounded by solvent molecules. Lattice energy, ΔH lat, is the energy required to break up the crystal lattice.īreaking up the lattice is an endothermic process. Step 2: The solute particle is surrounded by solvent molecules. Step 1: A particle of solute, such as an ion or molecule, breaks away from the lattice. The process of dissolving a solid solute in a liquid solvent can therefore be thought of as occurring in two steps: Solute particles in the solution are said to be in a higher state of entropy than solute particles making up the lattice. The solute particles in the solution are in constant motion and distributed more or less randomly throughout the solution so that the amount of disorder has increased compared to when they were part of the lattice. When this solute dissolves in a solvent, particles such as ions must be removed from the lattice and each solute particle must then be completely surrounded by solvent molecules. This is referred to as a low entropy state (3). The amount of disorder, or randomness, in a system is known as its entropy.Ī lattice is highly ordered, that is, the particles making up the lattice are in a low state of disorder. You are probably already familiar with representations of ionic compounds in which positive ions (cations) and negative ions (anions) are arranged in a lattice held together by electrostatic forces of attraction known as ionic bonds. The molecules or ions making up a solid solute exist in a highly ordered state which is referred to as a lattice. Theory Behind Determining Molar Enthalpy of Solution No ads = no money for us = no free stuff for you! (ii) ΔH is positive if energy (heat) is absorbed ( endothermic). ![]() (i) ΔH is negative if energy (heat) is released ( exothermic). Note: You must include the sign for ΔH soln (either + or −) Q = amount of energy (heat) released or absorbed ΔH soln = molar enthalpy (heat) of solution Step 3: Calculate mount of energy (heat) released or absorbed per mole of solute (ΔH soln) ![]() Q = amount of energy released or absorbed Step 1: Calculate the amount of energy released or absorbed (q) ⚛ To calculate the molar enthalpy of solution (molar heat of solution) using experimental data: ⚛ Enthalpy (heat) of solution can be determined in the laboratory by measuring the temperature change of the solvent when solute is added. ![]() ⚛ If heat is released when the solute dissolves, temperature of solution increases, reaction is exothermic, and ΔH is negative (ΔH 0). ⚛ Molar heat of solution (molar enthalpy of solution) has the units (2) J mol -1 or kJ mol -1 ![]() ⚛ Heat of solution (enthalpy of solution) has the symbol (1) ΔH soln ⚛ Molar heat of solution, or, molar enthalpy of solution, is the energy released or absorbed per mole of solute being dissolved in solvent. ⚛ Heat of solution, or, enthalpy of solution, is the energy released or absorbed when the solute dissolves in the solvent. ⚛ A solute dissolves in excess solvent to form a solution: ![]() ![]() ![]() Subscriptions will be charged to your credit card through your iTunes account.SBQ Cloud Subscription - unlimited project storage for access anytime, anywhere, on any device for.Subscribe now to SBQ Cloud and your first month is free. Your cloud subscription will open the door to unlimited upload/download storage of your projects for easy access to your projects on both your desktop and your iPad. Now upload and download through our SBQ Cloud. StoryBoard Quick DIRECT is a great tool for when the inspiration hits you when you're on the go. ![]() Upload your storyboards to your own cloud and open them right onto your desktop for editing and sharing in the latest versions of StoryBoard Quick or StoryBoard Artist where you can substitute characters, add more elements, import your script and more. Now, you can even take your mobile storyboards and work on them in your copy of StoryBoard Quick or StoryBoard Artist. Upload to your desktop StoryBoard Quick and StoryBoard Artist! Rearrange frames with the swipe of your finger and jump to any frame in the sequence for additional editing. View your entire project as thumbnails in the overview window. Set and save the frame duration, sit back and watch the show. Want to see your storyboards in motion? Just press play and watch your storyboard sequence play back on your mobile device. Set the font, font size and font color and your captions can be visible during playback as well! ![]() Zoom-in, Zoom-out and add directional arrows to define the action or camera movement.Įvery frame has its own caption for director's note or dialog. Even add more characters from our popular desktop versions. StoryBoard Quick Direct comes with great-looking looking actors in multiple positions and rotations so blocking the shot is a snap. Insert any photo on your iPhone or iPad to use as a location/backdrop or when something inspires you, take a photo right where you are and use it instantly! The HD version for your iPad boasts a bigger, Hi-Def interface to make composing your storyboards even easier! Plan your shots with the best pro storyboarding tool for the iPadįrom the creators of the #1 desktop storyboarding application, PowerProduction Software, comes the mobile app designed to assist filmmakers of every level compose shot ideas – on the go! StoryBoard Quick Direct turns your iPad into a mobile pre-visualization tool that will allow you to create and show off your storyboards and cinematic ideas, wherever you are! And, as a bonus, import them into your laptop application and keep boarding. ![]() ![]() For example, the London Ambulance Service sees a jump in assaults on ambulance staff during holidays where hundreds of drunk revelers stress the West End ambulance servicewith up to 300 calls an hour during the Christmas holiday. Identify hot spots where the chance of assault is higher due to the community or activities within the community. Consider the use of body cams to document these encounters.Įstablish a “may-day” response for crews in trouble. Make changes in how your agency identifies and responds to calls in high-risk areas. Improve your individual situational awareness and “street smarts” ![]() Get trained to defend yourself from attack. We should follow Australia’s approach of reporting and prosecuting every incident. The literature indicates that most assaults against ems caregivers and firefighters are not reported or entered into the criminal justice system. Kip Teitsort founder of DT4EMS provides this video “ EMS/Fire Assault Compilation 4.17″ ( use this link) They are also acquiring ballistic vests and getting de-escalation training. In May 2018, the Seattle Fire Department added a fire company to respond with an ambulance in the Pioneer Square community that includes shelters, camps, and a large homeless population. In 2015 a Detroit ambulance crew was attacked and severely injured by the companion of a patient. ![]() The paramedic sitting in the captain’s chair felt a slug impact the seat frame between her legs. followed by gunfire.īut what do you do when you have placed the patient on the stretcher and a “cousin” shows up and threatens violence to the patient or the responders? An inner-city fire-based ambulance crew had the experience of a “cousin” coming up as the ambulance was about to close the rear doors of the rig and shoot the patient. Or, in the case of Chicago Ambulance 75 last May, a crowd of relatives banging on the back of the ambulance. So is meeting the occupant of an apartment who aims a gun at you and orders you to leave. Every week a crew that is operating at a routine incident suddenly finds themselves in a Hot Zone because of a new player or situation, most of these encounters do not make the news.ĭo ems caregivers and firefighters “ Run, Hide or Fight” when they are suddenly in a Hot Zone?ĭiscovering a propane tank shooting a tongue of flame from its relief valve while searching at a structure fire is probably a Run response. This past week provided two vivid on-the-X situations: an active shooter and a raging firestorm. ![]() The goal is to get off the X as soon as possible. Getting off the X is a phrase used in the Tactical Emergency Casualty Care course that defines casualties and caregivers that are in the Hot Zone and exposed to life-threatening harm from the danger the situation poses. ![]() |